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Jeffry S Schumm

from Lafayette, IN
Age ~58

Jeffry Schumm Phones & Addresses

  • 5408 Stuart Ct, Lafayette, IN 47905 (765) 447-6815
  • La Fayette, IN
  • West Columbia, SC
  • Spartanburg, SC
  • Pekin, IL
  • Columbia, SC
  • 5408 Stuart Ct, Lafayette, IN 47905

Work

Position: Service Occupations

Education

Degree: High school graduate or higher

Publications

Us Patents

Silane Compound For Use In The Synthesis Of Semiconducting Polymers With Perpendicularly Arranged Cores And Method Of Synthesizing Said Compound

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US Patent:
51439930, Sep 1, 1992
Filed:
Aug 5, 1991
Appl. No.:
7/740319
Inventors:
James M. Tour - Columbia SC
Ruilian Wu - Columbia SC
Jeffry S. Schumm - Columbia SC
Assignee:
University of South Carolina - Columbia SC
International Classification:
C08G 7706
US Classification:
528 15
Abstract:
The stereochemical structure necessary for preparation of perpendicularly arranged cores is provided by a compound of the formula ##STR1## wherein X is a reactive group through which polymeric subunits can be bonded to the compound. In particular, X is advantageously Br. This compound can be synthesized by the reaction of tetrakis(3'-trimethylsilyl-2'-propynyl)silane with zirconocene dichloride and n-butyllithium and adding sulfur monochloride to the reaction product. This produces an adduct in which X is SiMe. sub. 3. This adduct may be converted to the bromo compound by reaction with bromine. The tetrakis(3'-trimethylsilyl-2'-propynyl)silane may be prepared by forming a magnesium Grignard reagent from 3-bromo-1-trimethylsilylpropyne and reacting the Grignard reagent with silicon tetrachloride.

Silane Compound For Use In The Synthesis Of Semiconducting Polymers With Perpendicular Arranged Cores

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US Patent:
50596950, Oct 22, 1991
Filed:
Mar 12, 1990
Appl. No.:
7/492543
Inventors:
James M. Tour - Columbia SC
Ruilian Wu - Columbia SC
Jeffry S. Schumm - Columbia SC
Assignee:
The University of South Carolina - Columbia SC
International Classification:
C07D52100
US Classification:
549 4
Abstract:
The stereochemical structure necessary for preparation of perpendicularly arranged cores is provided by a compound of the formula ##STR1## wherein X is a reactive group through which polymeric subunits can be bonded to the compound. In particular, X is advantageously Br. This compound can be synthesized by the reaction of tetrakis(3'-trimethylsilyl-2'-propynyl)silane with zirconocene dichloride and n-butyllithium and adding sulfur monochloride to the reaction product. This produces an adduct in which X is SiMe. sub. 3. This adduct may be converted to the bromo compound by reaction with bromine. The tetrakis(3'-trimethylsilyl-2-propynyl)silane may be prepared by forming a magnesium Grignard reagent from 3-bromo-1-trimethylsilylpropyne and reacting the Grignard reagent with silicon tetrachloride.

Compound For Use In The Synthesis Of Semiconducting Polymers With Perpendicularly Arranged Cores And Method Of Synthesizing Said Compound

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US Patent:
50268945, Jun 25, 1991
Filed:
Mar 12, 1990
Appl. No.:
7/492549
Inventors:
James M. Tour - Columbia SC
Ruilian Wu - Columbia SC
Jeffry S. Schumm - Columbia SC
Assignee:
University of South Carolina - Columbia SC
International Classification:
C07C30300
C07C 2200
C08G 7606
US Classification:
558 46
Abstract:
The stereochemical structure necessary for preparation of perpendicularly arranged cores is provided by a compound of the formula ##STR1## This compound can be synthesized by the reaction of ##STR2## with bromine in the presence of FeCl. sub. 3.
Jeffry S Schumm from Lafayette, IN, age ~58 Get Report