Marie E Picci

6335304, Jan 1, 2002

Nov 9, 1999

09/436827

Zhiqiang Alex He - Ridgefield CT
Werner J. Blank - Wilton CT
Marie Emmanuelle Picci - Norwalk CT

KIng Industries, INC - Norwalk CT

B01J 3100

502162, 502150, 502156, 502159, 502161, 502171, 502172, 525438, 525533, 525534, 525934, 528 87, 528 88, 528 89, 528 92, 528220, 528236, 528237, 528242

A metal (M) alkyl acid phosphate catalyst for the reaction of an epoxy compound with a carboxyl compound to provide a coating formulation that is stable at room temperature; that is humidity resistant, and non-yellowing, wherein the alkyl acid phosphate has the formula: and wherein: a. each R is selected from the group consisting of: i) a C to C alkly, cycloalkyl, or aryl; ii) a linear or branched C to C alkyl substituted with â(OâCH âCH â) or â(OâCHâCH âCH â) , wherein o or p is from 1 to 20; iii) a -hydroxyethyl compound, RââXâCH âCHâOHâCH â, wherein Râ is a C to C alkyl or cycloalkyl or aryl, X is either âCH â, âOâ or âCOOâ; b. n+m=3 and n is between 2 to 1; and c. M is Zn or Sn (II) in a mole equivalent of 0. 7 to 1.

6353057, Mar 5, 2002

Feb 10, 1999

09/247363

Zhiqiang He - Ridgefield CT
Werner J. Blank - Wilton CT
Marie E. Picci - Norwalk CT

King Industries, INc. - Norwalk CT

C08K 320

525124, 523415, 524555, 525528

A method of catalyzing a cationic coating comprising a cationic resin such as an epoxy resin-amine reaction product or a copolymer of a cationic monomer, and a blocked polyisocyanate, wherein a catalyst is added, said catalyst selected from the group consisting of bismuth carboxylate(s) having a hydrocarbon chain of from 11 to 36 carbon atoms and a molecular weight of from 165-465, and a mixture of a bismuth salt selected from the group consisting of bismuth oxide and bismuth chloride, and a carboxylic acid having a hydrocarbon chain of from 11 to 36 carbon atoms and a molecular weight of from 165-465.

58468978, Dec 8, 1998

Mar 19, 1997

8/820120

Werner Blank - Wilton CT
Zhiqiang Alex He - Ridgefield CT
Marie Emmanuelle Picci - Norwalk CT
John James Florio - Norwalk CT

King Industries, Inc. - Norwalk CT

B01J 3122

502150

The present invention is directed to novel metal organocomplexes as catalysts for the reaction of compounds with isocyanate and hydroxy functional groups to form urethane and/or polyurethane and the process employing such catalysts. More particularly, the present invention is directed to novel complexes of zirconium or hafnium with diketones or alkylacetoacetoates. These novel catalysts are useful for the production of urethanes and polyurethanes which are important in many industrial applications, such as: coatings, foams, adhesives, sealants, and reaction injection molding (RIM) plastics.

59656867, Oct 12, 1999

Aug 24, 1998

9/139205

Werner Blank - Wilton CT
Zhiqiang Alex He - Ridgefield CT
Marie Emmanuelle Picci - Norwalk CT
John James Florio - Norwalk CT

King Industries, Inc. - Norwalk CT

C08G 1822

528 56

The present invention is directed to novel metal organocomplexes as catalysts for the reaction of compounds with isocyanate and hydroxy functional groups to form urethane and/or polyurethane and the process employing such catalysts. More particularly, the present invention is directed to novel complexes of zirconium or hafnium with diketones or alkylacetoacetoates. These novel catalysts are useful for the production of urethanes and polyurethanes which are important in many industrial applications, such as: coatings, foams, adhesives, sealants, and reaction injection molding (RIM) plastics.